VALENCE ELECTRONS, the ones that reside in the outermost electron shell of an atom.
As you sit reading this sentence, billions of atoms surround you. When any two of them approach each other, their outermost electrons come into close contact. Recall that electrons are negatively charged particles, so a chance meeting between atoms usually results in the two repelling each other. Occasionally, however, atoms will stick together by forming a chemical bond.
There are two main types of bonding discussed here. A COVALENT BOND results when two atoms "share" valence electrons between them. An IONIC BOND occurs when one atom gains a valence electron from a different atom, forming a negative ion (ANION) and a positive ion (CATION), respectively. These oppositely charged ions are attracted to each other, forming an ionic bond.