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Why? Great question! It happens by the numbers in this case, electronegativity values. The covalent bonds between nonmetal atoms have relatively low differences in electronegativity values. Looking at the periodic table (again!) reveals that electronegativity values for the nonmetals generally range from 2.0 to 4.0 (with a few exceptions). Because the electronegativity values are fairly similar for all nonmetal atoms, they should have low differences in electronegativity values. For example, a carbon-oxygen bond has an electronegativity difference of 1.0. (Want proof? Check the table!) This value is considered rather low.
Guess what happens with ionic bonds because they usually occur between a metal and a nonmetal atom? The periodic table shows that metal atoms generally have electronegativity values that range from 0.7 to 1.5. The difference in electronegativity between metal and nonmetal atoms in an ionic bond is therefore relatively high compared to the difference in covalent bonds. For example, a common ionic solid is table salt (NaCl). The difference in electronegativity values for sodium and chlorine is 2.1. This value for the ionic bond between sodium and chlorine is two times greater than the value of 1.0 for the covalent carbon-oxygen bond. Try It Out!Identify the following bonds as covalent, ionic, or polar covalent:Just for Fun!
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